Matches in SemOpenAlex for { <https://semopenalex.org/work/W2051212553> ?p ?o ?g. }
- W2051212553 endingPage "2646" @default.
- W2051212553 startingPage "2631" @default.
- W2051212553 abstract "Comparing the acceleration effects of (4+2)-, (3+2)- and (2+2)-cycloaddition reactions in the presence of the salts of two types: gallium chloride in inert solvents and lithium perchlorate (LP) in diethyl ether (DE) it was observed that in the presence of GaCl3 the acceleration effect is approximately the same (104 times) for the studied reactions, while in LPDE medium for the same reactions strong increase (up to 104 times), weak increase or even decrease of the rate and equilibrium constants take place even with the common dienophile depending on the nature of the second reagent. It was suggested that the acceleration effect of cycloaddition reactions in the presence of such Lewis acids as aluminum, gallium or boron halides is due to the sharp increase of π-acceptor properties of dienophiles and therefore increasing energy of orbital interaction, whereas LPDE medium demonstrates strong stabilization of static and/or dynamic polar forms and favors reactions with charge control." @default.
- W2051212553 created "2016-06-24" @default.
- W2051212553 creator A5013993469 @default.
- W2051212553 creator A5028465281 @default.
- W2051212553 creator A5045365585 @default.
- W2051212553 creator A5053000721 @default.
- W2051212553 creator A5065077680 @default.
- W2051212553 creator A5073660914 @default.
- W2051212553 date "1998-03-01" @default.
- W2051212553 modified "2023-10-12" @default.
- W2051212553 title "The nature of lithium perchlorate and gallium chloride salt effect in cycloaddition reactions" @default.
- W2051212553 cites W1981084838 @default.
- W2051212553 cites W1987273307 @default.
- W2051212553 cites W1995308900 @default.
- W2051212553 cites W2003468085 @default.
- W2051212553 cites W2011857139 @default.
- W2051212553 cites W2019988550 @default.
- W2051212553 cites W2022502916 @default.
- W2051212553 cites W2030726872 @default.
- W2051212553 cites W2035664087 @default.
- W2051212553 cites W2045413386 @default.
- W2051212553 cites W2059239687 @default.
- W2051212553 cites W2087450721 @default.
- W2051212553 cites W2088516790 @default.
- W2051212553 cites W2090046268 @default.
- W2051212553 cites W2090391132 @default.
- W2051212553 cites W2145374329 @default.
- W2051212553 cites W2327062163 @default.
- W2051212553 cites W2334795449 @default.
- W2051212553 cites W2950074916 @default.
- W2051212553 cites W2951168503 @default.
- W2051212553 cites W3154291764 @default.
- W2051212553 doi "https://doi.org/10.1016/s0040-4020(98)00025-8" @default.
- W2051212553 hasPublicationYear "1998" @default.
- W2051212553 type Work @default.
- W2051212553 sameAs 2051212553 @default.
- W2051212553 citedByCount "26" @default.
- W2051212553 countsByYear W20512125532012 @default.
- W2051212553 countsByYear W20512125532013 @default.
- W2051212553 countsByYear W20512125532015 @default.
- W2051212553 countsByYear W20512125532016 @default.
- W2051212553 countsByYear W20512125532021 @default.
- W2051212553 crossrefType "journal-article" @default.
- W2051212553 hasAuthorship W2051212553A5013993469 @default.
- W2051212553 hasAuthorship W2051212553A5028465281 @default.
- W2051212553 hasAuthorship W2051212553A5045365585 @default.
- W2051212553 hasAuthorship W2051212553A5053000721 @default.
- W2051212553 hasAuthorship W2051212553A5065077680 @default.
- W2051212553 hasAuthorship W2051212553A5073660914 @default.
- W2051212553 hasConcept C134018914 @default.
- W2051212553 hasConcept C145148216 @default.
- W2051212553 hasConcept C147789679 @default.
- W2051212553 hasConcept C161790260 @default.
- W2051212553 hasConcept C163638829 @default.
- W2051212553 hasConcept C17525397 @default.
- W2051212553 hasConcept C178790620 @default.
- W2051212553 hasConcept C179104552 @default.
- W2051212553 hasConcept C185592680 @default.
- W2051212553 hasConcept C2776371256 @default.
- W2051212553 hasConcept C2778541603 @default.
- W2051212553 hasConcept C2778695967 @default.
- W2051212553 hasConcept C2779664164 @default.
- W2051212553 hasConcept C2780624963 @default.
- W2051212553 hasConcept C2780709120 @default.
- W2051212553 hasConcept C2780990938 @default.
- W2051212553 hasConcept C40875361 @default.
- W2051212553 hasConcept C52859227 @default.
- W2051212553 hasConcept C550372918 @default.
- W2051212553 hasConcept C71924100 @default.
- W2051212553 hasConcept C75473681 @default.
- W2051212553 hasConceptScore W2051212553C134018914 @default.
- W2051212553 hasConceptScore W2051212553C145148216 @default.
- W2051212553 hasConceptScore W2051212553C147789679 @default.
- W2051212553 hasConceptScore W2051212553C161790260 @default.
- W2051212553 hasConceptScore W2051212553C163638829 @default.
- W2051212553 hasConceptScore W2051212553C17525397 @default.
- W2051212553 hasConceptScore W2051212553C178790620 @default.
- W2051212553 hasConceptScore W2051212553C179104552 @default.
- W2051212553 hasConceptScore W2051212553C185592680 @default.
- W2051212553 hasConceptScore W2051212553C2776371256 @default.
- W2051212553 hasConceptScore W2051212553C2778541603 @default.
- W2051212553 hasConceptScore W2051212553C2778695967 @default.
- W2051212553 hasConceptScore W2051212553C2779664164 @default.
- W2051212553 hasConceptScore W2051212553C2780624963 @default.
- W2051212553 hasConceptScore W2051212553C2780709120 @default.
- W2051212553 hasConceptScore W2051212553C2780990938 @default.
- W2051212553 hasConceptScore W2051212553C40875361 @default.
- W2051212553 hasConceptScore W2051212553C52859227 @default.
- W2051212553 hasConceptScore W2051212553C550372918 @default.
- W2051212553 hasConceptScore W2051212553C71924100 @default.
- W2051212553 hasConceptScore W2051212553C75473681 @default.
- W2051212553 hasIssue "11" @default.
- W2051212553 hasLocation W20512125531 @default.
- W2051212553 hasOpenAccess W2051212553 @default.
- W2051212553 hasPrimaryLocation W20512125531 @default.
- W2051212553 hasRelatedWork W1551605947 @default.
- W2051212553 hasRelatedWork W1968047474 @default.
- W2051212553 hasRelatedWork W1987353477 @default.