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- W2051212595 abstract "Resonance Raman and 129I Mossbauer spectroscopy have been applied to the phenothiazine–iodine (PT–In) complexes, which exhibit relatively low electrical resistivities. It is shown from the resonance Raman spectra that the two iodine species in the PT–I3 and PT–I2.6 complexes are present in essentially the same chemical form, consisting of a distorted I3− unit and an I2 unit strongly coordinated to the I3− unit. The 129I Mossbauer spectrum, consistent with the results of the Raman spectra, suggests that the PT–I2.6 complex can be approximately formulated as (PT)53+[(I3)3(I2)2]3−, in which about three electrons per five PT molecules are transferred to the iodine and the transferred electrons are delocalized on the thirteen iodine atoms. The radical salt is recognized as a partially oxidized mixed-valence compound. The formation of the complex is quite similar to that of the perylene–I3 complex, which has a low electrical resistivity." @default.
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- W2051212595 date "1987-03-01" @default.
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- W2051212595 title "Resonance Raman and<sup>129</sup>I Mössbauer Spectroscopic Study of Phenothiazine–Iodine Complexes" @default.
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- W2051212595 doi "https://doi.org/10.1246/bcsj.60.857" @default.
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