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• W2051213053 abstract "A series of systematically-varied ‘rigid-rod’ octahedral ruthenium acetylide complexes, bearing the strong acceptor substituent -NO2, of general formula rans-[Ru(C  CC6H4R-4)2(dppm)2] (R  NO2, C6H4NO2-4, C6H4CHCHC 4CHCHC6H4NO2-4, (E) has been synthesized. X-ray structural studies of trans-[Ru(CCC6H4R-4)2(dppm)2] (RNO2. C6H4NO2-4) confirm the trans-disposed geometry of the acetylide ligands and, for the latter, non-planarity of the biphenylene groups. The mixed acetylide ‘rigid-rod’ complex trans-[Ru(C  CPh)(CCC6H4NO2-4)(dppm)2] has also been prepared. Semiempirical calculations employing zindo were performed on the mixed-acetylide complex, the results suggesting that the effect of trans-disposed ligands on the molecular quadratic hyperpolarizability β is not additive." @default.
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• W2051213053 date "1996-10-01" @default.
• W2051213053 modified "2023-10-18" @default.
• W2051213053 title "Organometallic complexes for nonlinear optics VI: syntheses of rigid-rod ruthenium σ-acetylide complexes bearing strong acceptor ligands; X-ray crystal structures of trans-[Ru(C  CC6H4NO2-4)2(dppm)2] and trans-[Ru(CCC6H4C6H4NO2-4,4′)2(dpppm)2]" @default.
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• W2051213053 doi "https://doi.org/10.1016/0022-328x(96)06384-x" @default.
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