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- W2051216857 abstract "The authors present a comprehensive review of the instances of the use of water in palladium catalysts and examine the three major protocols used. An outline of the function of water is included. The chapter features the recent progress in the chemistry of solid-bound Pd-catalyzed processes, with a focus on those customarily carried out in a homogeneous system, especially carbon–carbon bond-forming reactions. The review consists of three parts: rationale and need for immobilizing palladium on a solid support; comparison of various palladium immobilization systems; and applications for these solid-bound palladium catalysts in organic chemistry. Some of the authors' personal speculations about the future of this burgeoning field are also included. An extensive overview on the use of Pd-catalyzed and Pd-mediated reactions in solid phase combinatorial chemistry and parallel synthesis is provided. The discussion of reactions on soluble polymers such as MeO–PEG (polyethylene glycol) and some modern separation techniques (fluorous phase developments) are covered in three parts. The first part presents Pd-catalyzed and Pd-mediated transformations on solid support without cleaving off any higher molecular weight compound from the support. Techniques for the attachment of building blocks and simple group transformations, such as hydrogenation reactions, are also included. The second part covers cleavage reactions that give rise to soluble products as well as transformations that occur after the cleavage step. Finally, new separation techniques that enhance the throughput for automated parallel synthesis is reviewed." @default.
- W2051216857 created "2016-06-24" @default.
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- W2051216857 date "2005-03-02" @default.
- W2051216857 modified "2023-10-18" @default.
- W2051216857 title "Palladium Catalysts Immobilized on Polymeric Supports" @default.
- W2051216857 doi "https://doi.org/10.1002/0471212466.ch144" @default.
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