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• W2051217110 endingPage "1921" @default.
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• W2051217110 abstract "Reaction of [CpM(NAr)(PMe3)2] (M = Nb, Ta; Ar = 2,6-C6H3iPr2) with HSiClMe2 gives two remarkably different nonclassical Si···H···M products depending only on the identity of M; [CpTa(NAr)(H)(SiMe2Cl)(PMe3)] possesses an unusual electron-rich M−H···Si interligand hypervalent interaction while [CpNb{η3-N(Ar)SiMe2−H}Cl(PMe3)] is the first example of a β-agostic silylamine Si−H···M interaction showing a “stretched” Si−H bond." @default.
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• W2051217110 date "2000-09-01" @default.
• W2051217110 modified "2023-09-25" @default.
• W2051217110 title "Contrasting Nonclassical Silicon−Hydrogen Interactions in Niobium and Tantalum Half-Sandwich Complexes: Si−H···M Agostic versus M−H···Si−Cl Interligand Hypervalent Interactions" @default.
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• W2051217110 doi "https://doi.org/10.1002/1099-0682(200009)2000:9<1917::aid-ejic1917>3.0.co;2-m" @default.
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