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- W2051217215 abstract "Reaction of Cp*2Fe2(CO)4 with red selenium (Se8) afforded an unexpected selenium-rich triiron complex Cp*3Fe3Se5(1). Air oxidation of 1 in the presence of NH4PF6 gave the monocationic complex [Cp*3Fe3Se5] (PF6) (2). An X-ray crystal structure analysis of 2 revealed that an Fe3Se5 core consists of three iron atoms, one μ2-selenide ligand, and two μ3-diselenide ligands with a side-on manner. Reactions of 2 with some simple reagents were also examined." @default.
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- W2051217215 date "1998-04-01" @default.
- W2051217215 modified "2023-10-18" @default.
- W2051217215 title "Synthesis and Reactivity of Triiron Complexes Containing Selenide and Diselenide Bridging Ligands: X-ray Structure of [Cp<sup>*</sup><sub>3</sub>Fe<sub>3</sub>(μ<sub>2</sub>-Se)(μ<sub>3</sub>-Se<sub>2</sub>)<sub>2</sub>](PF<sub>6</sub>)(Cp<sup>*</sup>=η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)" @default.
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- W2051217215 doi "https://doi.org/10.1246/cl.1998.309" @default.
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