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- W2051218930 abstract "Pooled Fischer assay samples of shale oil from two seams in the oil shale deposit at Rundle, Queensland, were chemically separated into ten fractions and analysed by gas chromatography-mass spectrometry. Over 500 compounds were identified, including homologous series of straight-chain alkanes, 1-, 2- and 3-alkenes, nitriles, methyl ketones, amides and substituted cyclopentanes, cyclohexanes, benzenes, naphthalenes, pyridines and quinolines. The oils are highly aliphatic in character (HC = 1.6 –1.7); alkanes (≈30 wt%) and alkenes (≈20 wt%) are the most abundant components in the oil, with the straight-chain alkanes and 1-alkenes predominating. The most highly aromatic fractions were found, by proton n.m.r., to be those which contain phenols and heterocyclic nitrogen compounds and which constitute less than 5% of the oil. Approximately half of the nitrogen in the shale oil was present as neutral nitrogen compounds such as aliphatic nitriles and amides. The carbon chain length distributions of the alkanes, nitriles and methyl ketones are bimodal indicating origins from both algal and higher-plant sources, with algal sources predominating. The pyrolytic origin of prominent and unusual components such as nitriles, amides, 1-alkenes and methyl ketones is discussed. This is the first detailed chemical analysis of an Australian shale oil." @default.
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- W2051218930 date "1982-02-01" @default.
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- W2051218930 title "Chemical characterization of shale oil from Rundle, Queensland" @default.
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- W2051218930 doi "https://doi.org/10.1016/0016-2361(82)90233-2" @default.
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