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- W2051219289 abstract "Transition-metal-catalyzed trimethylenemethane (TMM) [3 + 2] cycloadditions provide direct routes to functionalized cyclopentanes. This reaction has been shown to be a highly chemo-, regio-, and diastereoselective process. We report a palladium-catalyzed asymmetric [3 + 2] trimethylenemethane (TMM) cycloaddition between 3-acetoxy-2-trimethylsilylmethyl-1-propene and various di- and trisubstituted olefins. Yields of exo-methylenecyclopentane products range from 59 to 99%, and enantiomeric excesses range from 58 to 92% ee." @default.
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- W2051219289 date "2006-09-22" @default.
- W2051219289 modified "2023-10-10" @default.
- W2051219289 title "Palladium-Catalyzed Asymmetric [3 + 2] Trimethylenemethane Cycloaddition Reactions" @default.
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- W2051219289 doi "https://doi.org/10.1021/ja0640750" @default.
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