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- W2051219512 abstract "The equilibrium between octahedral and tetrahedral cobalt (II) has been studied in H2O- HCl, H2O-HClO4-HCl, H2O-KCNS solutions and in R2O-B2O3, R2O-SiO2, R2O-Al2O3-SiO2, and CaO- B2O3-Al2O3 glasses. In aqueous solution, cobalt (II) absorption, in the region 10 to 25 kK, increases with increased addition of HCl or KCNS. In R2O-B2O3 and R2O-SiO2 glasses absorption of cobalt (II) increases with increased addition of R2O. In R2O-Al2O3-SiO2 and CaO-B2O3-Al2O3 glasses the total absorption area and the relative area of the resolved band around 15 kK (characteristic of tetrahedral cobalt (II) decrease with increased substitution of Al2O3 for SiO2 or B2O3. However, in CaO-B2O3-Al2O3 glasses containing a high proportion of Al2O3 and CaO, the octahedral-tetrahedral equilibrium of cobalt (II) behaved differently.In all the systems of solutions and glasses the total absorption area from 10 to 25 kK or the relative area of the resolved band around 15 kK (4A2)(F) → 4T1(P) could be used as a qualitative measure of the octahedral-tetrahedral equilibrium of cobalt (II]." @default.
- W2051219512 created "2016-06-24" @default.
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- W2051219512 date "1971-01-01" @default.
- W2051219512 modified "2023-09-25" @default.
- W2051219512 title "Cobalt as Colour Indicator in Glass" @default.
- W2051219512 cites W2318459123 @default.
- W2051219512 doi "https://doi.org/10.1080/0371750x.1971.10840763" @default.
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