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• W2051219661 endingPage "8939" @default.
• W2051219661 startingPage "8927" @default.
• W2051219661 abstract "Addition of H2S and H2Se, in different proportions, to aqueous Cd(ClO4)2 solutions containing (NaPO3)6 led to the formation of coupled composite CdS−CdSe nanoparticles. Conversely, the sequential introduction of different amounts of H2S and H2Se (or H2Se and H2S) into aqueous Cd(ClO4)2 solutions containing (NaPO3)6 produced core−shell type (CdS)CdSe [or (CdSe)CdS] nanoparticles. These structural assignments were based on spectroscopic (absorption, transmission, excitation, and emission), electrochemical, pulse radiolytic, and electron microscopic measurements. Conditions were adjusted (by adding excess cadmium and hydroxide ions) for the maximization of excitonic fluorescence. Two emission bands were observed in the coupled and in the core−shell type mixed semiconductor nanoparticles. The first one, centered around 470 nm, was attributed to the 1se−1sh excitonic emission of CdS. The second, centered around 560 nm, was proposed to arise from charge transfer of CdS to the coupled composite CdS−CdSe and core−shell type (CdS)CdSe [or (CdSe)CdS] nanoparticles." @default.
• W2051219661 created "2016-06-24" @default.
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• W2051219661 date "1996-01-01" @default.
• W2051219661 modified "2023-10-16" @default.
• W2051219661 title "Coupled Composite CdS−CdSe and Core−Shell Types of (CdS)CdSe and (CdSe)CdS Nanoparticles" @default.
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• W2051219661 doi "https://doi.org/10.1021/jp951965l" @default.
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