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- W2051220015 abstract "Abstract The title compound is readily prepared from the rhenium carboxylate, (dppe)(CO)3ReC(O)OCH3, by prolonged stirring of a solution of the carboxylate in benzene/H2O or THF/H2O. The reaction involves the unusual in situ conversion of ReC bonds to ReO bonds. The X-ray structure of the title compound shows that the μ2,η2-carbonato ligand is present in the symmetrical syn, syn conformation in the solid state in contrast to the alternate syn, anti geometry reported for the related complex, (diars)(CO)3ReOC(O)ORe(CO)3(diars)." @default.
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- W2051220015 date "1998-01-01" @default.
- W2051220015 modified "2023-09-24" @default.
- W2051220015 title "The preparation and crystal structure of (dppe) (CO)3Re-OC(O)O-Re(CO)3(dppe)" @default.
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- W2051220015 doi "https://doi.org/10.1016/s0277-5387(97)00356-2" @default.
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