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• W2051222917 abstract "Current studies have attributed the remarkable performance of polycrystalline ${mathrm{CuInSe}}_{2}$ (CIS) to anomalous grain-boundary (GB) physics in CIS. The recent theory predicts that GBs in CIS are hole barriers, which prevent GB electrons from recombining. We examine the atomic structure and chemical composition of (112) GBs in $mathrm{Cu}(mathrm{In},mathrm{Ga}){mathrm{Se}}_{2}$ (CIGS) using high-resolution $Z$-contrast imaging and nanoprobe x-ray energy-dispersive spectroscopy. We show that the theoretically predicted Cu-vacancy rows are not observed in (112) GBs in CIGS. Our first-principles modeling further reveals that the (112) GBs in CIS do not act as hole barriers. Our results suggest that the superior performance of polycrystalline CIS should not be explained solely by the GB behaviors." @default.
• W2051222917 created "2016-06-24" @default.
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• W2051222917 date "2006-05-22" @default.
• W2051222917 modified "2023-09-26" @default.
• W2051222917 title "Grain-Boundary Physics in PolycrystallineCuInSe2Revisited: Experiment and Theory" @default.
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• W2051222917 doi "https://doi.org/10.1103/physrevlett.96.205501" @default.
• W2051222917 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16803181" @default.
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