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• W2051223355 abstract "Abstract A practical method for N-methylation of NH-containing heterocycles using an environmentally safe and less toxic methylating reagent, dimethyl carbonate, has been developed. N,N,N′,N′-tetramethylethylenediamine (TMEDA), an extremely active organocatalyst for the methylation of imides, indoles, benzimidazoles, and piperazines in conjunction with dimethyl carbonate, can lead to N-methylation products with high conversion. The reaction sequence consists of competing alkylation and acylation pathways and involves TMEDA as a nucleophilic catalyst. A possible reaction mechanism is discussed based on the reaction results." @default.
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• W2051223355 date "2011-09-14" @default.
• W2051223355 modified "2023-10-16" @default.
• W2051223355 title "N-Methylation of NH-Containing Heterocycles with Dimethyl Carbonate Catalyzed by TMEDA" @default.
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• W2051223355 doi "https://doi.org/10.1080/00397911.2010.523151" @default.
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