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- W2051227323 abstract "(Diphenylmethyl)alkylketone werden durch Komplexe aus Lithiumalanat und cis-2,3-Pinandiol asymmetrisch reduziert. Die optischen Ausbeuten sind von der Struktur des Ketons abhängig. Die Stereoselektivität der Reduktion ist durch die Einführung eines Benzyloxyrests in das chirale Reagens entscheidend zu beeinflussen. Asymmetric Reductions, II. Reduction of Diphenylmethyl Alkyl Ketones by Complexes Prepared from Lithium Alanate and cis-2,3-Pinanediol Asymmetric reductions of diphenylmethyl alkyl ketones can be achieved by reagents prepared from lithium alanate and cis-2,3-pinanediol. The optical yields depend on the structure of the ketones. The stereoselectivity of the reduction can be influenced substantially by introduction of a benzyloxy substituent into the chiral reagent." @default.
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- W2051227323 date "1973-04-01" @default.
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- W2051227323 title "Asymmetrische Reduktionen, II. Reduktion von (Diphenylmethyl)alkylketonen mit Komplexen aus Lithiumalanat und <i>cis</i> ‐2,3‐Pinandiol" @default.
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- W2051227323 doi "https://doi.org/10.1002/cber.19731060429" @default.
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