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• W2051229967 abstract "Gold-catalyzed cyclizations of O-propioloyl oximes via C-N bond formation followed by arylidene group transfer were successfully carried out to afford the corresponding 4-arylideneisoxazol-5(4H)-ones in good to excellent yields. As an example, (E)-benzaldehyde O-3-phenylpropioloyl oxime (1a) was reacted in acetonitrile at 25 degrees C in the presence of Au(PPh(3))NTf(2) (5 mol %) to give 4-benzylidene-3-phenylisoxazol-5(4H)-one (2a) in 90% yield. On the basis of crossover experiments, the arylidene migration was shown to proceed in an intermolecular manner." @default.
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• W2051229967 date "2010-04-30" @default.
• W2051229967 modified "2023-10-18" @default.
• W2051229967 title "Gold-Catalyzed Cyclization and Subsequent Arylidene Group Transfer of <i>O</i>-Propioloyl Oximes" @default.
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• W2051229967 doi "https://doi.org/10.1021/ol100581m" @default.
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