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• W2051231569 abstract "The relative yield of the molecular ions (HCF2+ and DCF2+) produced by the bond-forming reaction between HD and CF22+ has been determined as a function of the collision energy from 0.17 to 0.62 eV in the centre-of-mass frame. At low collision energies, this chemical reaction exhibits an intramolecular isotope effect favouring the formation of DCF2+. This isotope effect increases in strength with decreasing collision energy and at the lowest collision energies we detect approximately twice as many DCF2+ as HCF2+ ions. One possible explanation of this observation is that electron transfer precedes the bond-forming step of the chemical reaction." @default.
• W2051231569 created "2016-06-24" @default.
• W2051231569 creator A5036343437 @default.
• W2051231569 creator A5047425268 @default.
• W2051231569 date "1998-09-01" @default.
• W2051231569 modified "2023-09-24" @default.
• W2051231569 title "Intramolecular isotope effects in the bond-forming reaction of CF22+ with HD" @default.
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• W2051231569 doi "https://doi.org/10.1016/s0009-2614(98)00873-2" @default.
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