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- W2051233805 abstract "The additions of some keto-carbene to a triple bond were studied. Since keto-carbene rearranges easily to a ketene derivative (Wolff rearrangement), the carbenic addition will always be in competition with the rearrangement. In the case of benzoylphenylcabene, the rearrangement is preferred, and no cyclopropene derivative is obtained. However, benzoyl and acetylcarbene, both having hydrogen instead of phenyl as a substituent, could be successfully added to diphenylacetylene and di-n-butylacetylene, thus giving 1, 2-disubstituted cyclopropene derivatives. Thus, it was found that the acylcyclopropenes were synthesized in a single step by the utilization of the carbenic addition of keto-carbene to a triple bond." @default.
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- W2051233805 date "1966-09-01" @default.
- W2051233805 modified "2023-09-27" @default.
- W2051233805 title "Cyclopropene Derivatives. II. The Reaction of Diazoketone with Triple Bond" @default.
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- W2051233805 doi "https://doi.org/10.1246/bcsj.39.1975" @default.
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