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• W2051235423 abstract "Various approaches were evaluated in order to eliminate the spectral interferences noted when Pt and Pd has to be determined in environmental dust samples by ICP-MS. The chemical separation of Pt and Pd from the matrix components on ion-exchange resins was applied. The performance of cation-exchange resins (Dowex 50 WX-8, Dowex 50 WX-2, Dowex HCR-S, Varion KS, Cellex-P) for the separation of interfering ions was then examined. It was found that Dowex 50 WX-8 shows best performance. The effects of mass, mesh number of resin and concentration of Cl− ions on matrix separation were also studied. Another approach was to use the anion-exchange sorbent Cellex-T, which allows almost total retention of both analytes followed by their elution with 0.1 mol L−1 thiourea in 1 mol L−1 HCl. This procedure however can be used only for platinum determination by ICP-MS. The accuracy of proposed procedures was confirmed by the analysis of certified material BCR-723, and then it was used for determination Pt and Pd in samples of road dust." @default.
• W2051235423 created "2016-06-24" @default.
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• W2051235423 date "2006-04-01" @default.
• W2051235423 modified "2023-09-30" @default.
• W2051235423 title "Elimination of interferences in determination of platinum and palladium in environmental samples by inductively coupled plasma mass spectrometry" @default.
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• W2051235423 doi "https://doi.org/10.1016/j.aca.2006.01.066" @default.
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