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• W2051236663 abstract "The propargylamine-cadmium chloride complex (HC  C-CH2NH3)2CdCl4 belongs to the family of bidimensional perovskite-type compounds which are able to show photoreactivity phenomena under irradiation (γ, X, u.v…) leading to a possible polymerization in the solid state due to the presence of triple bonds in the organic layer. The crystal structure of the complex, before reaction, has been solved by the X-ray diffraction method (monoclinic, C2c, a = 23.624 (6) Å, b = 7.367 (2) Å, c = 7.353 (4) Å, β = 98.89 (1)°, Z = 4). The distances between adjacent triple bonds (3.44–3.48 Å) are in the range of a possible formation of polyene structure initiated by a 7-6 addition and oriented to the b and/or →c directions. On the other hand, the complex exhibits, under the heating process, an exothermic phenomenon corresponding to the irreversible formation of a “high temperature” phase: the crystallographic characteristics of this new phase have been determined." @default.
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• W2051236663 date "1993-03-01" @default.
• W2051236663 modified "2023-09-25" @default.
• W2051236663 title "Thermal study and crystal structure of a perovskite-type unsaturated molecular composite: Propargylamine and cadmium chloride complex salt" @default.
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• W2051236663 doi "https://doi.org/10.1016/0022-3697(93)90268-v" @default.
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