FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2051237405> ?p ?o ?g. }

• W2051237405 endingPage "1427" @default.
• W2051237405 startingPage "1419" @default.
• W2051237405 abstract "The dinuclear complex (RPh[NPN]Ta)2(μ-H)4 (where RPh[NPN] = [RP(CH2SiMe2NPh)2] and R = Ph, Cy) shows remarkable reactivity with molecular nitrogen, producing the side-on end-on bound dinitrogen complex (RPh[NPN]Ta)2(μ-η1:η2-N2)(μ-H)2. This tantalum tetrahydride also promotes other small molecule activation. Addition of secondary phosphines HPR‘2 (R‘ = Ph, Cy) to (RPh[NPN]Ta)2(μ-H)4 accesses trihydride phosphide systems (RPh[NPN]Ta)2(μ-H)3(μ-PR‘2). Addition of primary phosphines H2PR‘ ‘ (R‘ ‘ = Cy, Ad) gives bridging phosphinidene tantalum complexes (RPh[NPN]Ta)2(μ-H)2(μ-PR‘ ‘). Molecular structures as determined by X-ray crystallography for the complexes (PhPh[NPN]Ta)2(μ-H)3(μ-PCy2) and (CyPh[NPN]Ta)2(μ-H)2(μ-PAd) are presented. Isotopic labeling studies offer mechanistic insights into the reactivity of this tetrahydride system. Reaction of Cy2PH with (CyPh[NPN]Ta)2(μ-D)4, for instance, gives solely the monohydride dideuteride complex (CyPh[NPN]Ta)2(μ-H)(μ-D)2(μ-PCy2). This labeling study indicates that D2 loss forms the reactive species, (CyPh[NPN]Ta)2(μ-D)2, which promotes small molecule activation. Addition of CyPH2 to (CyPh[NPN]Ta)2(μ-D)4 gives a series of isotopomers, with an average composition of 0.67 H and 1.33 D, supporting a 1,2-H2 elimination step to form the tantalum phosphinidenes. These results are tied into the general reactivity of (RPh[NPN]Ta)2(μ-H)4." @default.
• W2051237405 created "2016-06-24" @default.
• W2051237405 creator A5026785398 @default.
• W2051237405 creator A5088410702 @default.
• W2051237405 date "2005-03-01" @default.
• W2051237405 modified "2023-09-23" @default.
• W2051237405 title "Addition of Primary and Secondary Phosphines to Dinuclear Tantalum Hydrides: Synthesis of Phosphides and Phosphinidenes via P−H Bond Activation" @default.
• W2051237405 cites W1528907305 @default.
• W2051237405 cites W1964445020 @default.
• W2051237405 cites W1966636260 @default.
• W2051237405 cites W1973760295 @default.
• W2051237405 cites W1981892823 @default.
• W2051237405 cites W1983428335 @default.
• W2051237405 cites W1983644317 @default.
• W2051237405 cites W1984391069 @default.
• W2051237405 cites W1991233903 @default.
• W2051237405 cites W1998731653 @default.
• W2051237405 cites W1999195421 @default.
• W2051237405 cites W2000466466 @default.
• W2051237405 cites W2000506283 @default.
• W2051237405 cites W2003656667 @default.
• W2051237405 cites W2018120769 @default.
• W2051237405 cites W2020392305 @default.
• W2051237405 cites W2027891743 @default.
• W2051237405 cites W2029867206 @default.
• W2051237405 cites W2042763735 @default.
• W2051237405 cites W2042904388 @default.
• W2051237405 cites W2044235309 @default.
• W2051237405 cites W2045928772 @default.
• W2051237405 cites W2052199115 @default.
• W2051237405 cites W2058066731 @default.
• W2051237405 cites W2059020082 @default.
• W2051237405 cites W2073745132 @default.
• W2051237405 cites W2076857727 @default.
• W2051237405 cites W2078138234 @default.
• W2051237405 cites W2079762069 @default.
• W2051237405 cites W2084778578 @default.
• W2051237405 cites W2132003992 @default.
• W2051237405 cites W2133373474 @default.
• W2051237405 cites W2139490622 @default.
• W2051237405 cites W2159600674 @default.
• W2051237405 cites W2316154175 @default.
• W2051237405 cites W2319970034 @default.
• W2051237405 cites W2464424430 @default.
• W2051237405 cites W2950753705 @default.
• W2051237405 cites W3136190712 @default.
• W2051237405 doi "https://doi.org/10.1021/om0490076" @default.
• W2051237405 hasPublicationYear "2005" @default.
• W2051237405 type Work @default.
• W2051237405 sameAs 2051237405 @default.
• W2051237405 citedByCount "28" @default.
• W2051237405 countsByYear W20512374052012 @default.
• W2051237405 countsByYear W20512374052014 @default.
• W2051237405 countsByYear W20512374052015 @default.
• W2051237405 countsByYear W20512374052016 @default.
• W2051237405 countsByYear W20512374052017 @default.
• W2051237405 countsByYear W20512374052018 @default.
• W2051237405 countsByYear W20512374052019 @default.
• W2051237405 countsByYear W20512374052021 @default.
• W2051237405 crossrefType "journal-article" @default.
• W2051237405 hasAuthorship W2051237405A5026785398 @default.
• W2051237405 hasAuthorship W2051237405A5088410702 @default.
• W2051237405 hasConcept C127124265 @default.
• W2051237405 hasConcept C142724271 @default.
• W2051237405 hasConcept C155647269 @default.
• W2051237405 hasConcept C161790260 @default.
• W2051237405 hasConcept C178790620 @default.
• W2051237405 hasConcept C185592680 @default.
• W2051237405 hasConcept C204787440 @default.
• W2051237405 hasConcept C2776910235 @default.
• W2051237405 hasConcept C2780654602 @default.
• W2051237405 hasConcept C32909587 @default.
• W2051237405 hasConcept C514619126 @default.
• W2051237405 hasConcept C71240020 @default.
• W2051237405 hasConcept C71924100 @default.
• W2051237405 hasConcept C8010536 @default.
• W2051237405 hasConceptScore W2051237405C127124265 @default.
• W2051237405 hasConceptScore W2051237405C142724271 @default.
• W2051237405 hasConceptScore W2051237405C155647269 @default.
• W2051237405 hasConceptScore W2051237405C161790260 @default.
• W2051237405 hasConceptScore W2051237405C178790620 @default.
• W2051237405 hasConceptScore W2051237405C185592680 @default.
• W2051237405 hasConceptScore W2051237405C204787440 @default.
• W2051237405 hasConceptScore W2051237405C2776910235 @default.
• W2051237405 hasConceptScore W2051237405C2780654602 @default.
• W2051237405 hasConceptScore W2051237405C32909587 @default.
• W2051237405 hasConceptScore W2051237405C514619126 @default.
• W2051237405 hasConceptScore W2051237405C71240020 @default.
• W2051237405 hasConceptScore W2051237405C71924100 @default.
• W2051237405 hasConceptScore W2051237405C8010536 @default.
• W2051237405 hasIssue "7" @default.
• W2051237405 hasLocation W20512374051 @default.
• W2051237405 hasOpenAccess W2051237405 @default.
• W2051237405 hasPrimaryLocation W20512374051 @default.
• W2051237405 hasRelatedWork W1965092487 @default.
• W2051237405 hasRelatedWork W1976253167 @default.
• W2051237405 hasRelatedWork W2009996801 @default.
• W2051237405 hasRelatedWork W2027409960 @default.

• next