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- W2051239862 abstract "The reactions of Ru(CO)4PPh3 and Ru(CO)5 under pressures of hydrogen have been studied using a high-pressure spectrophotometric cell. Infrared spectral evidence has been obtained for the formation of H2Ru(CO)3PPh3 in reversible equilibrium with Ru(CO)4PPh3 and hydrogen. Reaction of Ru(CO)5 with hydrogen at low temperatures affords H2Ru(CO)4 as the initial product; above 20° decomposition occurs resulting in the formation of polynuclear products." @default.
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- W2051239862 date "1973-08-01" @default.
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- W2051239862 title "Infrared spectroscopic evidence for dihydridotricarbonyl(triphenylphosphine)ruthenium" @default.
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- W2051239862 doi "https://doi.org/10.1016/s0022-328x(00)89985-4" @default.
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