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- W2051241925 abstract "Abstract Enantiospecific total synthesis of (-)-megaphone ( 1 ) is reported. The key synthetic tactic is the use of (4 S )-2 Z -ethylidene-4-trityloxymethyl-butan-4-olide ( 6 ) to both establish the relative and absolute stereochemistry of the contiguous tertiary and quaternary carbon centers by a highly controlled 1,4- and 1,3-asymmetric induction and construct the 4-methoxy-6,6-dialkyl-cyclohexenone portion of 1 ." @default.
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- W2051241925 date "1985-01-01" @default.
- W2051241925 modified "2023-10-17" @default.
- W2051241925 title "Enantiospecific total synthesis of (-)-megaphone by a highly controlled consecutive 1,4- and 1,3-asymmetric induction" @default.
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- W2051241925 doi "https://doi.org/10.1016/s0040-4039(00)61960-3" @default.
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