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- W2051244240 abstract "Aryl and alkyl β-heteroatom-trisubstituted vinyl triflones react with THF and cyclohexane to undergo trifluoromethyl radical-mediated C−H functionalization reactions to afford E and Z β-heteroatom-trisubstituted olefins. Most reactions proceed with both high yield and high stereospecificity (retention of configuration). β-Substituents which have been employed in this study are iodine, bromine, fluorine, benzoate, ethylcarbonate, and phthalimide. β-Substituents bearing powerful electron-releasing groups such as alkoxy or amino render the vinyl triflone unreactive." @default.
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- W2051244240 date "1997-05-01" @default.
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- W2051244240 title "Stereospecific Alkenylation of C−H Bonds via Reaction with β-Heteroatom-Functionalized Trisubstituted Vinyl Triflones<sup>1</sup>" @default.
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- W2051244240 doi "https://doi.org/10.1021/ja963636s" @default.
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