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- W2051244352 abstract "At high supercoolings, isotactic polystyrene and polybutene-1 have a rounded crystal shape, suggesting kinetic roughening. Still, the growth rates of these polymer crystals show the supercooling dependence derived for nucleation controlled growth. On the other hand, isotactic poly-4-methylpentene-1 1,4 trans-polybutadiene at higher crystallization temperatures and polyethylene at high pressures show a rounded crystal shape: thermal roughening. Again, the growth rate is described by the nucleation theory. On the basis of these observations, we propose a crystallization kinetics taking account of the entropic barrier that was originally proposed by Sadler." @default.
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- W2051244352 date "2003-01-08" @default.
- W2051244352 modified "2023-09-28" @default.
- W2051244352 title "Morphology, Growth Rate, and Lamellar Thickness of Polymer Crystals" @default.
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- W2051244352 doi "https://doi.org/10.1081/mb-120021611" @default.
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