Matches in SemOpenAlex for { <https://semopenalex.org/work/W2051255648> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W2051255648 endingPage "83" @default.
- W2051255648 startingPage "79" @default.
- W2051255648 abstract "The reaction of N-lithiated aminoboranes of type R2BN(tBu)Li (R Me, Mes) with Diorganylgallium chlorides R′2GaCl(R′ Me, Et, CH2C(Ph)Me2) yields the N-borylated gallium amides R′2GaN(tBu)BR2. A single crystal X ray structure determination did show the molecule Mes2BN(tBu)GaEt2 to be monomeric with trigonal planar coordinated gallium, nitrogen and boron atoms. The BN bond length is short (1.384(6) Å), the GaN bond length is rather long (1.937(3) Å), although the nitrogen is non bridging. The described compounds are the first well characterized examples of monomeric gallium monoamides, on the other hand they represent a new class of compounds having two different elements of the III main group bound to one nitrogen atom. Die Umsetzung von N-lithiierten Aminoboranen des Types R2BN(tBu)Li (R Me, Mes) mit Diorganylgalliumchloriden R′2GaCl(R′ Me, Et, CH2C(Ph)Me2) ergibt am Stickstoff-Atom borylierte Galliumamide R′2GaN(tBu)BR2. Eine Einkristall- Röntgenstrukturanalyse ergab, daβ das Molekül Mes2BN(tBu)GaEt2 monomer vorliegt und trigonal planar koordinierte Gallium- Stickstoff- und Bor-Atome enthält. Die BN-Bindung ist kurz (1.384(6) Å), die GaN-Bindung ist dagegen lang (1.937(3) Å), wenn man berücksichtigt, daβ das Stickstoff-Atom nicht verbrückend zwischen zwei Gallium-Atomen wirkt. Diese Verbindungen sind nicht nur erste Beispiele für monomere Galliummonoamide, sondern auch erste Vertreter einer Verbindungsklasse, bei der zwei verschiedene Elemente der III. Hauptgruppe an ein Stickstoff-Atom gebunden sind." @default.
- W2051255648 created "2016-06-24" @default.
- W2051255648 creator A5016336576 @default.
- W2051255648 date "1994-02-01" @default.
- W2051255648 modified "2023-10-18" @default.
- W2051255648 title "Darstellung und struktur monomerer N-borylierter Galliumamide" @default.
- W2051255648 cites W1484258286 @default.
- W2051255648 cites W1965716259 @default.
- W2051255648 cites W1983974686 @default.
- W2051255648 cites W1993581416 @default.
- W2051255648 cites W1994664711 @default.
- W2051255648 cites W2008771997 @default.
- W2051255648 cites W2014776173 @default.
- W2051255648 cites W2015756544 @default.
- W2051255648 cites W2039262591 @default.
- W2051255648 cites W2042729741 @default.
- W2051255648 cites W2048305460 @default.
- W2051255648 cites W2050431481 @default.
- W2051255648 cites W2052239005 @default.
- W2051255648 cites W2067411296 @default.
- W2051255648 cites W2073560631 @default.
- W2051255648 cites W2074211830 @default.
- W2051255648 cites W2084598592 @default.
- W2051255648 cites W2087248114 @default.
- W2051255648 cites W2093322274 @default.
- W2051255648 cites W2144917551 @default.
- W2051255648 cites W2158452717 @default.
- W2051255648 cites W2317703412 @default.
- W2051255648 cites W2324537474 @default.
- W2051255648 doi "https://doi.org/10.1016/0022-328x(94)87039-x" @default.
- W2051255648 hasPublicationYear "1994" @default.
- W2051255648 type Work @default.
- W2051255648 sameAs 2051255648 @default.
- W2051255648 citedByCount "14" @default.
- W2051255648 countsByYear W20512556482018 @default.
- W2051255648 countsByYear W20512556482021 @default.
- W2051255648 crossrefType "journal-article" @default.
- W2051255648 hasAuthorship W2051255648A5016336576 @default.
- W2051255648 hasConcept C115624301 @default.
- W2051255648 hasConcept C155647269 @default.
- W2051255648 hasConcept C166940927 @default.
- W2051255648 hasConcept C178790620 @default.
- W2051255648 hasConcept C185592680 @default.
- W2051255648 hasConcept C194185919 @default.
- W2051255648 hasConcept C2780378348 @default.
- W2051255648 hasConcept C2993420144 @default.
- W2051255648 hasConcept C32909587 @default.
- W2051255648 hasConcept C521977710 @default.
- W2051255648 hasConcept C537208039 @default.
- W2051255648 hasConcept C550372918 @default.
- W2051255648 hasConcept C71240020 @default.
- W2051255648 hasConcept C8010536 @default.
- W2051255648 hasConceptScore W2051255648C115624301 @default.
- W2051255648 hasConceptScore W2051255648C155647269 @default.
- W2051255648 hasConceptScore W2051255648C166940927 @default.
- W2051255648 hasConceptScore W2051255648C178790620 @default.
- W2051255648 hasConceptScore W2051255648C185592680 @default.
- W2051255648 hasConceptScore W2051255648C194185919 @default.
- W2051255648 hasConceptScore W2051255648C2780378348 @default.
- W2051255648 hasConceptScore W2051255648C2993420144 @default.
- W2051255648 hasConceptScore W2051255648C32909587 @default.
- W2051255648 hasConceptScore W2051255648C521977710 @default.
- W2051255648 hasConceptScore W2051255648C537208039 @default.
- W2051255648 hasConceptScore W2051255648C550372918 @default.
- W2051255648 hasConceptScore W2051255648C71240020 @default.
- W2051255648 hasConceptScore W2051255648C8010536 @default.
- W2051255648 hasIssue "1-2" @default.
- W2051255648 hasLocation W20512556481 @default.
- W2051255648 hasOpenAccess W2051255648 @default.
- W2051255648 hasPrimaryLocation W20512556481 @default.
- W2051255648 hasRelatedWork W1974203807 @default.
- W2051255648 hasRelatedWork W1992471639 @default.
- W2051255648 hasRelatedWork W1999011562 @default.
- W2051255648 hasRelatedWork W2012345717 @default.
- W2051255648 hasRelatedWork W2012675768 @default.
- W2051255648 hasRelatedWork W2075817299 @default.
- W2051255648 hasRelatedWork W2091436431 @default.
- W2051255648 hasRelatedWork W2326985701 @default.
- W2051255648 hasRelatedWork W2463657710 @default.
- W2051255648 hasRelatedWork W2942835415 @default.
- W2051255648 hasVolume "465" @default.
- W2051255648 isParatext "false" @default.
- W2051255648 isRetracted "false" @default.
- W2051255648 magId "2051255648" @default.
- W2051255648 workType "article" @default.