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- W2051257125 abstract "Abstract Under pressure La and Ce show effects due to varying degrees of 4f localization, much the same as occurs in the actinide series where the 5f states change from itinerant to localized with increasing atomic number. A self-consistent Linearized Augmented Plane Wave method is used to elucidate the 4f character under changes in atomic volume (i.e. pressure) for the fcc phases of both La and Ce. In both metals 4f occupation increases only slightly under pressure. The low temperature structural transitions of La under pressure correlate with changes of Fermi surface topology. The collapsed α-phase of Ce can be understood in terms of a band-like 4f state which participates weakly in bonding." @default.
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- W2051257125 date "1980-10-01" @default.
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- W2051257125 title "f-electron bonding, electronic structure and phase transitions in lanthanum and cerium" @default.
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- W2051257125 doi "https://doi.org/10.1016/0378-4363(80)90188-6" @default.
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