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- W2051257395 abstract "The chiral diphosphine 1 reacts with [(diolefin)Rh(THF) 2 ]PF 6 (diolefine: 1.5-cyclooctadiene, norbornadiene) to form the complexes 4 and 5. The structure of 4 was determined by single crystal X-ray analysis. 4 crystallizes in the monoclinic space group P2 1 . The lattice constants (at 180 K) are: a = 974.0(6); b = 3889.2(29); c = 1309.4(5) pm; β = 105.25(4)°. The hydrogenation of methyl-α-acetamidocinnamate in the presence of 5 yields (R)-N-acetylphenylalanine methyl ester with 33% enantiomeric excess." @default.
- W2051257395 created "2016-06-24" @default.
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- W2051257395 date "1989-08-01" @default.
- W2051257395 modified "2023-09-23" @default.
- W2051257395 title "Synthese neuer optisch aktiver Rh-Komplexe: Die Kristallstruktur von [(5S)-3,4-Bis(diphenylphosphino)-5-menthoxy-2(5H)-furanon](1,5-cyclooctadien)rhodium-hexafluorophosphat / Synthesis of New Optically Active Rh-Complexes: The Crystal Structure of [(5S)-3,4-Bis(diphenylphosphino)-5-menthoxy-2(5 H)-furanone](1,5-cyclooctadiene)rhodium-hexafluorophosphate" @default.
- W2051257395 doi "https://doi.org/10.1515/znb-1989-0804" @default.
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