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• W2051257490 abstract "Abstract 13 C NMR is employed to study the correlation between molecular dynamics and melting transition for the bulk ibuprofen and the confined ibuprofen in titania nanotubes. Under confinement, for all methyl-groups rotation remains unchanged and aromatic-ring flipping is slightly accelerated. The bulk ibuprofen melts at 351 K activating rapid molecular reorientation and rapid rotation of isobutyl-group while the confined ibuprofen completely becomes ‘liquid-like’ at 339 K activating also rapid rotation of isobutyl-group and restricted molecular reorientation. It suggests that confinement substantially changes the segmental dynamics which participates in melting transition but only slightly affects the others." @default.
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• W2051257490 date "2008-02-01" @default.
• W2051257490 modified "2023-09-23" @default.
• W2051257490 title "The molecular dynamics and melting transition of the confined ibuprofen in titania nanotube studied by NMR" @default.
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• W2051257490 doi "https://doi.org/10.1016/j.cplett.2008.01.007" @default.
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