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- W2051258972 abstract "The polarised single-crystal electronic spectra and e.s.r. spectra of six bis(ethylenediamine)copper(II) complexes have been interpreted in terms of a crystal field of D2h symmetry. The equatorial x- and y-co-ordinate axes were found to lie close to the copper–ligand bonds rather than between them, giving rise to a dx2–y2 ground state. In the Cu en2X2 complexes the sequence of one-electron energy levels is dx2–y2 > dz2 > dxzdyz with the position of the dxy orbital less certain, but probably lying between the dz2 and dxz,dyz levels. From the single-crystal e.s.r. spectra and the electronic energy levels the orbital reduction factors k⊥ and k∥ have been determined, and interpreted as molecular orbital coefficients." @default.
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- W2051258972 date "1969-01-01" @default.
- W2051258972 modified "2023-10-16" @default.
- W2051258972 title "The crystal-field energy levels of some bis(ethylenediamine)copper(II) complexes" @default.
- W2051258972 doi "https://doi.org/10.1039/j19690000319" @default.
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