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- W2051259856 endingPage "12165" @default.
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- W2051259856 abstract "The development of efficient methods for the generation of enantioenriched sulfonamides and sulfones is an important objective for fields such as organic synthesis and medicinal chemistry; however, there have been relatively few reports of direct catalytic asymmetric approaches to controlling the stereochemistry of the sulfur-bearing carbon of such targets. In this report, we describe nickel-catalyzed stereoconvergent Negishi arylations and alkenylations of racemic α-bromosulfonamides and -sulfones that furnish the desired cross-coupling product in very good ee and yield for an array of reaction partners. Mechanistic studies are consistent with the generation of a radical intermediate that has a sufficient lifetime to diffuse out of the solvent cage and to cyclize onto a pendant olefin." @default.
- W2051259856 created "2016-06-24" @default.
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- W2051259856 creator A5021393078 @default.
- W2051259856 creator A5058584967 @default.
- W2051259856 date "2014-08-15" @default.
- W2051259856 modified "2023-10-17" @default.
- W2051259856 title "Stereoconvergent Arylations and Alkenylations of Unactivated Alkyl Electrophiles: Catalytic Enantioselective Synthesis of Secondary Sulfonamides and Sulfones" @default.
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- W2051259856 doi "https://doi.org/10.1021/ja506885s" @default.
- W2051259856 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4151784" @default.
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- W2051259856 hasPublicationYear "2014" @default.
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