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- W2051260210 abstract "Spiropyran (SP) is a type of photochromic molecules widely studied because of their interesting physical and chemical properties. Irradiation of spiropyrans with near UV-light induces heterolytic cleavage of the spiro bond, resulting in the possibility of their application in electro-optical molecular devices and electronic data storage. Although some reports conclude that the opening process also occurs upon electrochemical oxidation of the indolic nitrogen, a complete description of both oxidation and reduction processes, is yet unavailable. In this work, cyclic voltammetry was employed for characterizing nitrospiropyran structures. After oxidation of SP, a reduction signal at a potential value less negative than the original closed compound appeared when successive voltammetric cycles were performed. Based on the results obtained, possible mechanistic pathways are discussed." @default.
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- W2051260210 date "2014-01-01" @default.
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- W2051260210 title "Electrochemical Characterization of Spiropyran Structures" @default.
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- W2051260210 doi "https://doi.org/10.1016/j.proche.2014.12.039" @default.
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