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• W2051260322 endingPage "2873" @default.
• W2051260322 startingPage "2870" @default.
• W2051260322 abstract "The reduction of dipyridil[3,2-a:2'3'-c]phenazine, dppz, by pulse radiolytically generated e(-)(sol) or by the reaction of the dppz excited states with electron donors produces the radical dppzH(.). The dimer radical, (dppz)(2)H(.), exists in equilibrium with dppz with an association constant, K = 10(3) M(-1). The rate constant for the reaction of dppzH(.) with dppz is k = 4.3 x 10(6) M(-1) s(-1). DFT calculations on the structures of dppzH(.) and the doubly reduced and doubly protonated dppzH(2) rendered a planar structure for the former species and a bent one for the latter." @default.
• W2051260322 created "2016-06-24" @default.
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• W2051260322 date "2006-03-03" @default.
• W2051260322 modified "2023-10-18" @default.
• W2051260322 title "On the Association and Structure of Radicals Derived from Dipyridil[3,2-<i>a</i>:2‘3‘-<i>c</i>]phenazine. Contrast between the Electrochemical, Radiolytic, and Photochemical Reduction Processes" @default.
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• W2051260322 doi "https://doi.org/10.1021/jo051985b" @default.
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• W2051260322 hasPublicationYear "2006" @default.
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