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- W2051264817 abstract "Abstract The effect of reactor materials on the catalytic performance of the isosynthesis was investigated. Al 2 O 3 and several calcium salts promoted zirconium dioxide-based catalysts were prepared by mechanical mixing method and evaluated in the isosynthesis reaction in a quartz-lined stainless-steel tubular reactor and a stainless-steel tubular reactor, respectively. It was found that stainless-steel tubular reactor seriously affected the selectivity of isosynthesis, while quartz-lined stainless-steel tubular reactor was favorable for the formation of i-C 4 hydrocarbons and suppressing the formation of CO 2 . The addition of Al 2 O 3 into ZrO 2 could largely enhance the activity while maintain the i-C 4 selectivity of pure ZrO 2 . CaF 2 or CaSO 4 , as an additive promoted the formation of i-C 4 , in the meantime maintains the activity of pure ZrO 2 . The influence of reaction temperatures on the catalytic performance of the catalysts in the quartz-lined stainless-steel tubular reactor was also investigated." @default.
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- W2051264817 date "2004-04-01" @default.
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- W2051264817 title "Erratum to “Influence of reactor materials on i-C4 synthesis from CO hydrogenation over ZrO2 based catalysts” [Fuel Process. Technol. 83 (1–3) (2003) 39–48]" @default.
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- W2051264817 doi "https://doi.org/10.1016/j.fuproc.2003.08.001" @default.
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