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• W2051264872 endingPage "16792" @default.
• W2051264872 startingPage "16784" @default.
• W2051264872 abstract "Abstract Phenanthroline‐based hexadentate ligands L 1 and L 2 bearing two achiral semicarbazone or two chiral imine moieties as well as the respective mononuclear complexes incorporating various lanthanide ions, such as La III , Eu III , Tb III , Lu III , and Y III metal ions, were synthesized, and the crystal structures of [ML 1 Cl 3 ] (M=La III , Eu III , Tb III , Lu III , or Y III ) complexes were determined. Solvent or water molecules act as coligands for the rare‐earth metals in addition to halide anions. The big Ln III ion exhibits a coordination number (CN) of 10, whereas the corresponding Eu III , Tb III , Lu III , and Y III centers with smaller ionic radii show CN=9. Complexes of L 2 , namely [ML 2 Cl 3 ] (M=Eu III , Tb III , Lu III , or Y III ) ions could also be prepared. Only the complex of Eu III showed red luminescence, whereas all the others were nonluminescent. The emission properties of the Eu derivative can be applied as a photophysical signal for sensing various anions. The addition of phosphate anions leads to a unique change in the luminescence behavior. As a case study, the quenching behavior of adenosine‐5′‐triphosphate (ATP) was investigated at physiological pH value in an aqueous solvent. A specificity of the sensor for ATP relative to adenosine‐5′‐diphosphate (ADP) and adenosine‐5′‐monophosphate (AMP) was found. 31 P NMR spectroscopic studies revealed the formation of a [EuL 2 (ATP)] coordination species." @default.
• W2051264872 created "2016-06-24" @default.
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• W2051264872 date "2012-11-13" @default.
• W2051264872 modified "2023-10-18" @default.
• W2051264872 title "Lanthanide(III) Complexes of Bis-semicarbazone and Bis-imine-Substituted Phenanthroline Ligands: Solid-State Structures, Photophysical Properties, and Anion Sensing" @default.
• W2051264872 cites W146689122 @default.
• W2051264872 cites W1971987676 @default.
• W2051264872 cites W1973899508 @default.
• W2051264872 cites W1976750965 @default.
• W2051264872 cites W1979823162 @default.
• W2051264872 cites W1981941593 @default.
• W2051264872 cites W1981957537 @default.
• W2051264872 cites W1987062630 @default.
• W2051264872 cites W1988501179 @default.
• W2051264872 cites W1990412045 @default.
• W2051264872 cites W1990665850 @default.
• W2051264872 cites W1991813895 @default.
• W2051264872 cites W1998172507 @default.
• W2051264872 cites W1999139342 @default.
• W2051264872 cites W2003312805 @default.
• W2051264872 cites W2005105191 @default.
• W2051264872 cites W2010623066 @default.
• W2051264872 cites W2012086002 @default.
• W2051264872 cites W2012492137 @default.
• W2051264872 cites W2015681525 @default.
• W2051264872 cites W2016828206 @default.
• W2051264872 cites W2021727710 @default.
• W2051264872 cites W2022842176 @default.
• W2051264872 cites W2025269455 @default.
• W2051264872 cites W2025317154 @default.
• W2051264872 cites W2026880039 @default.
• W2051264872 cites W2027427640 @default.
• W2051264872 cites W2033630329 @default.
• W2051264872 cites W2035799084 @default.
• W2051264872 cites W2038989965 @default.
• W2051264872 cites W2042575138 @default.
• W2051264872 cites W2044732667 @default.
• W2051264872 cites W2046935384 @default.
• W2051264872 cites W2054778552 @default.
• W2051264872 cites W2064823389 @default.
• W2051264872 cites W2065254594 @default.
• W2051264872 cites W2066151517 @default.
• W2051264872 cites W2066953497 @default.
• W2051264872 cites W2077372756 @default.
• W2051264872 cites W2079092539 @default.
• W2051264872 cites W2089718915 @default.
• W2051264872 cites W2094596026 @default.
• W2051264872 cites W2100042879 @default.
• W2051264872 cites W2102520893 @default.
• W2051264872 cites W2106976043 @default.
• W2051264872 cites W2107851804 @default.
• W2051264872 cites W2109519875 @default.
• W2051264872 cites W2112586170 @default.
• W2051264872 cites W2116050504 @default.
• W2051264872 cites W2118651298 @default.
• W2051264872 cites W2120796806 @default.
• W2051264872 cites W2138576711 @default.
• W2051264872 cites W2139760538 @default.
• W2051264872 cites W2149614962 @default.
• W2051264872 cites W2151859760 @default.
• W2051264872 cites W2154071625 @default.
• W2051264872 cites W2155819396 @default.
• W2051264872 cites W2158626917 @default.
• W2051264872 cites W2160489485 @default.
• W2051264872 cites W2164672308 @default.
• W2051264872 cites W2166071229 @default.
• W2051264872 cites W2280195996 @default.
• W2051264872 cites W2314895485 @default.
• W2051264872 cites W2949311230 @default.
• W2051264872 cites W2952639395 @default.
• W2051264872 cites W2953305835 @default.
• W2051264872 cites W3136336649 @default.
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• W2051264872 cites W4240488575 @default.
• W2051264872 cites W4249726227 @default.
• W2051264872 cites W4254202986 @default.
• W2051264872 cites W4255541300 @default.
• W2051264872 cites W4256723390 @default.
• W2051264872 cites W4321429477 @default.
• W2051264872 cites W54538561 @default.
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• W2051264872 doi "https://doi.org/10.1002/chem.201201705" @default.
• W2051264872 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23150237" @default.
• W2051264872 hasPublicationYear "2012" @default.
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