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- W2051265169 abstract "UV photolysis has been used to generate dinitrogen compounds by substitution of CO groups by N2 in supercritical fluid solvents (scXe, scCO2 and scC2H6) containing high pressures of N2. Compounds include Cp'Mn(CO)2L (Cp′ C5H4Me; L PMe3-xPhx, x = 0 to 3). A semi-quantitative comparison of the photolysis of Cp★Mn(CO)3 (Cp★ C5Me5) and N2 in ScXe and scCO2 indicates that there is little difference between the effectiveness of the photolysis in these two supercritical solvents. The Timney Ligand Effect approach is used to rationalise the fact that some of the ν(CO) and ν(NN) bands of Cp★Mn(CO)2(N2) and Cp★Mn(CO)(N2)2 are nearly coincident." @default.
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- W2051265169 date "1994-12-01" @default.
- W2051265169 modified "2023-10-16" @default.
- W2051265169 title "Organometallic photochemistry in supercritical fluids: Reactions of cyclopentadienyl carbonyl and phosphine carbonyl complexes of manganese with dinitrogen" @default.
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- W2051265169 doi "https://doi.org/10.1016/0022-328x(94)87196-5" @default.
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