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- W2051265395 abstract "The mechanical alloying process has been applied to preparing f.c.c. NiTiH3 solid solution alloy powders using a room-temperature rod mill under a reactive hydrogen gas atmosphere. The mechanically alloyed powders have been characterized by means of X-ray diffraction, optical microscopy, scanning electron microscopy, transmission electron microscopy and chemical analysis. During the first few kiloseconds (11 ks) of the rod milling time, the coarse powder particles of Ni and Ti disintegrated into several particles that have fresh surfaces. These fresh or new surfaces are very active and able to absorb hydrogen gas, so that h.c.p. Ti reacts completely with the hydrogen gas to form f.c.c. TiH2 with grain sizes of about 60 nm diameter. During the hydration process, the Ni powder particles are neutral and did not react with hydrogen (milling atmosphere). After a rod milling time of 43 ks, the f.c.c. TiH2 formed diffused into Ni matrix to form f.c.c. NiTiH3 solid solution with an average grain size of 10 nm diameter. This solid solution expands with increasing rod milling time (173 ks) and saturated to give a constant lattice parameter a0 of 0.354 03 nm after milling for 360 ks. The end product of the f.c.c. NiTiH3 solid solution consists of fine (1 μm in diameter) and homogeneous (spherical-like morphology) powder particles. In addition, the metallic hydride phase formed is very stable at temperatures as high as 993 K." @default.
- W2051265395 created "2016-06-24" @default.
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- W2051265395 date "1995-02-01" @default.
- W2051265395 modified "2023-09-27" @default.
- W2051265395 title "Mechanically assisted solid state hydrogenation for formation of nanocrystalline NiTiH3 alloy powders" @default.
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- W2051265395 doi "https://doi.org/10.1016/0925-8388(94)01367-5" @default.
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