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- W2051266106 abstract "A series of p-benzoquinones having an ester functional group in the α position of alkyl side chains was prepared. Irradiation of these quinones, except for methyl 3-methyl-2-(4-methyl-3,6-dioxo-1,4-cyclohexadienyl)-butyrate (3e), rapidly gave methyl 3-substituted 2,3-dihydro-5-hydroxybenzofuran-2-carboxylate in fairly good yields, and it was found that rearrangement of the side chain occurred concomitantly. Photolysis of quinone 3e afforded methyl 2-(2,5-dihydroxy-4-methylphenyl)-3-methyl-3-butenoate as the major product. An intermediate was postulated to account for the isolated photoproduct." @default.
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- W2051266106 date "1982-08-01" @default.
- W2051266106 modified "2023-09-27" @default.
- W2051266106 title "Synthesis of Dihydrobenzofuran Derivatives from Substituted<i>p</i>-Benzoquinones" @default.
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- W2051266106 doi "https://doi.org/10.1246/bcsj.55.2415" @default.
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