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• W2051268349 abstract "We report inelastic neutron scattering (INS) studies on a series of Mn(12) derivatives, [Mn(12)O(12)(O2CC6F5)16(H2O)4]z, in which the number of unpaired electrons in the cluster is varied. We investigated three oxidation levels: z = 0 for the neutral complex, z = -1 for the one-electron reduced species and z = -2 for the two-electron reduced complex. For z = 0, the ground state is S = 10 as in the prototypical Mn12-acetate. For z = -1, we have S = 19/2, and for z = - 2, an S = 10 ground state is retrieved. INS studies show that the axial zero-field splitting parameter D is strongly suppressed upon successive electron reduction: D = -0.45 cm(-1) (z = 0), D = -0.35 cm(-1) (z = -1), and D approximately -0.26 cm(-1) (z = -2). Each electron reduction step is directly correlated to the conversion of one anisotropic (Jahn-Teller distorted) Mn3+ (S = 2) to one nearly isotropic Mn2+ (S = 5/2)." @default.
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• W2051268349 date "2005-01-11" @default.
• W2051268349 modified "2023-10-18" @default.
• W2051268349 title "Inelastic Neutron Scattering Study of Electron Reduction in Mn₁₂ Derivatives" @default.
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• W2051268349 doi "https://doi.org/10.1021/ic048931p" @default.
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