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- W2051268350 abstract "(3R) and (3S) 3-deoxy-3-fluoro-7-phospho-D-arabino hept-2-ulosonic acids (3R and 3S-3F-DAHP) the 3-fluoro analogues of DAHP were synthesized from the corresponding 2-deoxy-2-fluoro hexose-6-phosphates. 3R- and 3S-3F-DAHP were tested as substrates for 3-dehydroquinate synthetase from E. coli. Determination of kinetic parameters showed that their apparent Km and Vm were in the same order of magnitude for these two compounds. Further conversion of 3R- and 3S-3F-DAHP into (6R) and (6S) 6-fluoro dehydroshikimate and (6R) and (6S) 6-fluoro shikimate, respectively, was investigated and results are discussed. Les acides (3R) et (3S) 3-désoxy-3-fluoro-7-phospho-D-arabino hept-2-ulosoniques (3R- et 3S-3F-DAHP), les 3-fluoro analogues du DAHP, ont été synthétisés à partir des 2-désoxy-2-fluoro hexose-6-phosphates correspondants. Ces 3R- et 3S-3F-DAHP ont été testés comme substrats de la 3-déhydroquinate synthétase d'E. coli. La détermination de leurs paramètres cinétiques a permis de montrer que Km apparent et Vm étaient du même ordre de grandeur pour ces deux composés. La conversion des 3R- et 3S-3F-DAHP respectivement en (6R) et (6S) 6-fluoro dehydroshikimate et en (6R) et (6S) 6-fluoro shikimate a été étudiée et les résultats obtenus sont discutés." @default.
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- W2051268350 date "1986-11-01" @default.
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- W2051268350 title "The shikimate pathway V. Fluorine-containing analogues of 3-deoxy-D-arabino hept-2-ulosonate-7-phosphate (DAHP)" @default.
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- W2051268350 doi "https://doi.org/10.1016/s0300-9084(86)80066-9" @default.
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