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• W2051268907 abstract "Abstract Primary and secondary electrophilic radicals such as : .CHRCO2CH3(R=H,CH3,CO2CH3) and tertiary .CCl3, radical were added directly at C-8 of, the model purine compound, caffeine to give the corresponding 8-substituted derivatives in fairly good yields. Unexpected reaction of caffeine with oxy radicals from the initiators (PhCo2., t-BuOO.) gave rise to C-5 substituted 1,3,7-trimethyl-5,7-dihydrouric acid derivatives (C-5-R=CCl3 CH3, C(CH3)2CO2CH3) and to the spirodihydantoin C-8 adduct derivative of caffeine 11 ." @default.
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• W2051268907 date "1989-01-01" @default.
• W2051268907 modified "2023-09-25" @default.
• W2051268907 title "Addition of electrophilic radicals to caffeine: synthetic aspects and influence of the peroxidic initiators" @default.
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• W2051268907 doi "https://doi.org/10.1016/0040-4020(89)80102-4" @default.
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