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- W2051275470 abstract "The theory of the effect of vibration-rotation interaction on spectral line intensities is extended from diatomic to linear molecules. This effect is calculated by the contact transformation method and is expressed by a parameter θk which is a sum of a term, which reduces to θ = μ0μ1re for a diatomic molecule, and an additional term due to the Coriolis force coupling different vibrations. A classical derivation of θk is also given, by which it is shown that θk is the ratio of effective charges excited perpendicularly, and in the direction of vibration. The results are applied to triatomic molecules and compared with the few presently existing experimental data." @default.
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- W2051275470 date "1963-01-01" @default.
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- W2051275470 title "Influence of vibration-rotation interaction on spectral line intensities of linear molecules" @default.
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- W2051275470 doi "https://doi.org/10.1016/0022-2852(63)90150-4" @default.
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