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• W2051275501 abstract "The title compound has been synthesised in powder form by two distinct methods: namely by sodiation of the parent amine 2,2,6,6-tetramethylpiperidine with n-butylsodium in a hydrocarbon solvent or by transmetallation from lithium 2,2,6,6-tetramethylpiperidide through the action of sodium t-butoxide in hexane solution. An alternative crystalline specimen suitable for X-ray crystallographic study was grown from a solution which additionally contained n,s-dibutylmagnesium. This study reveals a trimeric molecule of C3h symmetry, its salient feature being a strictly planar (NaN)3 ring. The sterically encumbered amide anions are separated by large NNaN bond angles of 143.76(6)°, the bonding in which is slightly asymmetrical (NaN bond lengths: 2.307(2) and 2.362(2) Å). Discussion focuses on the contrast between the tetrameric ring arrangement of the lithium congener, which was reported several years ago." @default.
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• W2051275501 date "1999-09-01" @default.
• W2051275501 modified "2023-09-27" @default.
• W2051275501 title "Synthesis and crystal structure of trimeric sodium 2,2,6,6-tetramethylpiperidide (NaTMP)" @default.
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• W2051275501 doi "https://doi.org/10.1016/s0022-328x(99)00284-3" @default.
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