Matches in SemOpenAlex for { <https://semopenalex.org/work/W2051278195> ?p ?o ?g. }
Showing items 1 to 82 of
82
with 100 items per page.
- W2051278195 abstract "Abstract Attempts to measure the conductivity of solid electrolytes having the composition RbCu 4 Cl 3+ x I 2− x where x =0 or 0.25 were carried out using copper and Chevrel phase electrodes Cu 2 Mo 6 S 8 . Complex impedance diagrams showed severe polarization effects at copper electrodes. Special programs were used with a computer coupled to the impedance meter allowing measurements at constant overpotential or constant current. In contrast to usual situations, the polarization at the copper electrode is a decreasing function of the ac signal voltage and a constant quantity of electrolysing current of ≈10 −2 C cm −2 is required to disrupt the blocking effect at the interface. Results obtained with the Chevrel phases unambiguously show that the exchange of ions between two solid phases can take place at room temperature without any interfacial overpotential. The best conductivity value of RbCu 4 Cl 3 I 2 was 0.475 (Ω cm) −1 at room temperature but all the measurements revealed a marked instability towards lower values. The conductivity of RbCu 4 Cl 3.25 I 1.75 at room temperature is 0.36 (Ω cm) −1 and is stable. The activation energy is 0.045 eV." @default.
- W2051278195 created "2016-06-24" @default.
- W2051278195 creator A5031150778 @default.
- W2051278195 creator A5033398189 @default.
- W2051278195 creator A5059380559 @default.
- W2051278195 date "1981-04-01" @default.
- W2051278195 modified "2023-09-26" @default.
- W2051278195 title "Conductivity of RbCu4Cl3+xI2−x and copper electrode reaction computerized complex analysis" @default.
- W2051278195 cites W2034419427 @default.
- W2051278195 cites W2055325139 @default.
- W2051278195 cites W2057046040 @default.
- W2051278195 cites W2085989312 @default.
- W2051278195 doi "https://doi.org/10.1016/0167-2738(81)90001-1" @default.
- W2051278195 hasPublicationYear "1981" @default.
- W2051278195 type Work @default.
- W2051278195 sameAs 2051278195 @default.
- W2051278195 citedByCount "6" @default.
- W2051278195 crossrefType "journal-article" @default.
- W2051278195 hasAuthorship W2051278195A5031150778 @default.
- W2051278195 hasAuthorship W2051278195A5033398189 @default.
- W2051278195 hasAuthorship W2051278195A5059380559 @default.
- W2051278195 hasConcept C109883240 @default.
- W2051278195 hasConcept C113196181 @default.
- W2051278195 hasConcept C119599485 @default.
- W2051278195 hasConcept C127413603 @default.
- W2051278195 hasConcept C131540310 @default.
- W2051278195 hasConcept C147789679 @default.
- W2051278195 hasConcept C17525397 @default.
- W2051278195 hasConcept C178790620 @default.
- W2051278195 hasConcept C185592680 @default.
- W2051278195 hasConcept C186460083 @default.
- W2051278195 hasConcept C205049153 @default.
- W2051278195 hasConcept C43617362 @default.
- W2051278195 hasConcept C52859227 @default.
- W2051278195 hasConcept C544778455 @default.
- W2051278195 hasConcept C68801617 @default.
- W2051278195 hasConcept C69990965 @default.
- W2051278195 hasConcept C95121573 @default.
- W2051278195 hasConceptScore W2051278195C109883240 @default.
- W2051278195 hasConceptScore W2051278195C113196181 @default.
- W2051278195 hasConceptScore W2051278195C119599485 @default.
- W2051278195 hasConceptScore W2051278195C127413603 @default.
- W2051278195 hasConceptScore W2051278195C131540310 @default.
- W2051278195 hasConceptScore W2051278195C147789679 @default.
- W2051278195 hasConceptScore W2051278195C17525397 @default.
- W2051278195 hasConceptScore W2051278195C178790620 @default.
- W2051278195 hasConceptScore W2051278195C185592680 @default.
- W2051278195 hasConceptScore W2051278195C186460083 @default.
- W2051278195 hasConceptScore W2051278195C205049153 @default.
- W2051278195 hasConceptScore W2051278195C43617362 @default.
- W2051278195 hasConceptScore W2051278195C52859227 @default.
- W2051278195 hasConceptScore W2051278195C544778455 @default.
- W2051278195 hasConceptScore W2051278195C68801617 @default.
- W2051278195 hasConceptScore W2051278195C69990965 @default.
- W2051278195 hasConceptScore W2051278195C95121573 @default.
- W2051278195 hasLocation W20512781951 @default.
- W2051278195 hasOpenAccess W2051278195 @default.
- W2051278195 hasPrimaryLocation W20512781951 @default.
- W2051278195 hasRelatedWork W1525433866 @default.
- W2051278195 hasRelatedWork W1771197839 @default.
- W2051278195 hasRelatedWork W1970142647 @default.
- W2051278195 hasRelatedWork W1986159647 @default.
- W2051278195 hasRelatedWork W2025566231 @default.
- W2051278195 hasRelatedWork W2037236374 @default.
- W2051278195 hasRelatedWork W2043800610 @default.
- W2051278195 hasRelatedWork W2048301506 @default.
- W2051278195 hasRelatedWork W2067323926 @default.
- W2051278195 hasRelatedWork W2080409583 @default.
- W2051278195 hasRelatedWork W2090343316 @default.
- W2051278195 hasRelatedWork W2092821384 @default.
- W2051278195 hasRelatedWork W2355818638 @default.
- W2051278195 hasRelatedWork W2912548377 @default.
- W2051278195 hasRelatedWork W2951174240 @default.
- W2051278195 hasRelatedWork W3098176069 @default.
- W2051278195 hasRelatedWork W3178018490 @default.
- W2051278195 hasRelatedWork W3183571836 @default.
- W2051278195 hasRelatedWork W3197327377 @default.
- W2051278195 hasRelatedWork W2186878125 @default.
- W2051278195 isParatext "false" @default.
- W2051278195 isRetracted "false" @default.
- W2051278195 magId "2051278195" @default.
- W2051278195 workType "article" @default.