Matches in SemOpenAlex for { <https://semopenalex.org/work/W2051279636> ?p ?o ?g. }
- W2051279636 endingPage "2123" @default.
- W2051279636 startingPage "2111" @default.
- W2051279636 abstract "The complex formation of α,ω-diaminopolyphosphonates (ethylenediamine- [H8edtmp], trimethylenediamine- [H8tdtmp] and hexamethylenediamine-N,N,N′,N′-tetramethylenetetraphosphonate [H8hdtmp]) with cobalt(III) polyamine complexes has been investigated by means of 31P NMR spectroscopy. The formation and protonation constants of the complexes and the 31P NMR chemical shifts of each protonated species were determined from the pH dependence of the 31P NMR signals. In any complexes, the nitrogen atom of the ligand is not coordinated to CoIII. The complex cis-[CoCl(en)2(NH3)]2+ forms a mononuclear O-monodentate complex and two types of binuclear bis(O-monodentate) complexes by a reaction with edtmp and tdtmp, and forms a mononuclear O-monodentate complex and a dinuclear bis(O-monodentate) complex with hdtmp. The complex cis-[CoCl2(en)2]+ forms a mononuclear O-monodentate complex and a mononuclear O,O-bidentate complex having an eight-membered chelate ring with edtmp and tdtmp, and forms a mononuclear O,O-bidentate complex and dinuclear bis(O-monodentate) complexes with hdtmp. In the case of the edtmp complexes, two iminodiphosphonate groups interact with each other: 1) an interaction between the nitrogen atoms of two imino fragments by a hydrogen bond (NH+···N) in a monoprotonated species and 2) an intramolecular interaction between the protonated nitrogen atom and phosphonate O− of another imino group (NH+···−OP) in triprotonated and tetraprotonated species." @default.
- W2051279636 created "2016-06-24" @default.
- W2051279636 creator A5037335231 @default.
- W2051279636 creator A5081230819 @default.
- W2051279636 date "1997-09-01" @default.
- W2051279636 modified "2023-09-26" @default.
- W2051279636 title "Structure and NMR Behavior of Cobalt(III) Polyamine Complexes of<i>α</i>,<i>ω</i>-Alkylenediamine-<i>N</i>,<i>N</i>,<i>N</i>′,<i>N</i>′-tetramethylenetetraphosphonate in Aqueous Solution" @default.
- W2051279636 cites W1636324519 @default.
- W2051279636 cites W1968440617 @default.
- W2051279636 cites W2028124815 @default.
- W2051279636 cites W2031936708 @default.
- W2051279636 cites W2042560074 @default.
- W2051279636 cites W2051544773 @default.
- W2051279636 cites W2056440127 @default.
- W2051279636 cites W2059423159 @default.
- W2051279636 cites W2064510868 @default.
- W2051279636 cites W2070899555 @default.
- W2051279636 cites W2073544814 @default.
- W2051279636 cites W2075614708 @default.
- W2051279636 cites W2079167403 @default.
- W2051279636 cites W2082468219 @default.
- W2051279636 cites W2088358131 @default.
- W2051279636 cites W2089733019 @default.
- W2051279636 cites W2095041467 @default.
- W2051279636 cites W2156973961 @default.
- W2051279636 cites W2165962113 @default.
- W2051279636 cites W2322055596 @default.
- W2051279636 cites W2328071160 @default.
- W2051279636 cites W2951118077 @default.
- W2051279636 cites W3137458885 @default.
- W2051279636 cites W3139400583 @default.
- W2051279636 doi "https://doi.org/10.1246/bcsj.70.2111" @default.
- W2051279636 hasPublicationYear "1997" @default.
- W2051279636 type Work @default.
- W2051279636 sameAs 2051279636 @default.
- W2051279636 citedByCount "12" @default.
- W2051279636 countsByYear W20512796362014 @default.
- W2051279636 countsByYear W20512796362016 @default.
- W2051279636 countsByYear W20512796362017 @default.
- W2051279636 countsByYear W20512796362018 @default.
- W2051279636 countsByYear W20512796362021 @default.
- W2051279636 crossrefType "journal-article" @default.
- W2051279636 hasAuthorship W2051279636A5037335231 @default.
- W2051279636 hasAuthorship W2051279636A5081230819 @default.
- W2051279636 hasConcept C103319777 @default.
- W2051279636 hasConcept C112887158 @default.
- W2051279636 hasConcept C115624301 @default.
- W2051279636 hasConcept C116569031 @default.
- W2051279636 hasConcept C145148216 @default.
- W2051279636 hasConcept C155647269 @default.
- W2051279636 hasConcept C170493617 @default.
- W2051279636 hasConcept C178516000 @default.
- W2051279636 hasConcept C178790620 @default.
- W2051279636 hasConcept C179104552 @default.
- W2051279636 hasConcept C185592680 @default.
- W2051279636 hasConcept C2780728571 @default.
- W2051279636 hasConcept C30095370 @default.
- W2051279636 hasConcept C32909587 @default.
- W2051279636 hasConcept C515602321 @default.
- W2051279636 hasConcept C55493867 @default.
- W2051279636 hasConcept C66974803 @default.
- W2051279636 hasConcept C71240020 @default.
- W2051279636 hasConcept C75079739 @default.
- W2051279636 hasConcept C8010536 @default.
- W2051279636 hasConceptScore W2051279636C103319777 @default.
- W2051279636 hasConceptScore W2051279636C112887158 @default.
- W2051279636 hasConceptScore W2051279636C115624301 @default.
- W2051279636 hasConceptScore W2051279636C116569031 @default.
- W2051279636 hasConceptScore W2051279636C145148216 @default.
- W2051279636 hasConceptScore W2051279636C155647269 @default.
- W2051279636 hasConceptScore W2051279636C170493617 @default.
- W2051279636 hasConceptScore W2051279636C178516000 @default.
- W2051279636 hasConceptScore W2051279636C178790620 @default.
- W2051279636 hasConceptScore W2051279636C179104552 @default.
- W2051279636 hasConceptScore W2051279636C185592680 @default.
- W2051279636 hasConceptScore W2051279636C2780728571 @default.
- W2051279636 hasConceptScore W2051279636C30095370 @default.
- W2051279636 hasConceptScore W2051279636C32909587 @default.
- W2051279636 hasConceptScore W2051279636C515602321 @default.
- W2051279636 hasConceptScore W2051279636C55493867 @default.
- W2051279636 hasConceptScore W2051279636C66974803 @default.
- W2051279636 hasConceptScore W2051279636C71240020 @default.
- W2051279636 hasConceptScore W2051279636C75079739 @default.
- W2051279636 hasConceptScore W2051279636C8010536 @default.
- W2051279636 hasIssue "9" @default.
- W2051279636 hasLocation W20512796361 @default.
- W2051279636 hasOpenAccess W2051279636 @default.
- W2051279636 hasPrimaryLocation W20512796361 @default.
- W2051279636 hasRelatedWork W1964544952 @default.
- W2051279636 hasRelatedWork W1980640176 @default.
- W2051279636 hasRelatedWork W1991357943 @default.
- W2051279636 hasRelatedWork W2010679546 @default.
- W2051279636 hasRelatedWork W2027402004 @default.
- W2051279636 hasRelatedWork W2035400525 @default.
- W2051279636 hasRelatedWork W2066215008 @default.
- W2051279636 hasRelatedWork W2084303224 @default.
- W2051279636 hasRelatedWork W2095096982 @default.
- W2051279636 hasRelatedWork W2410025030 @default.