FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2051279896> ?p ?o ?g. }

• W2051279896 endingPage "5356" @default.
• W2051279896 startingPage "5343" @default.
• W2051279896 abstract "A series of [Ir(C^N)2(bpy)][PF6] complexes in which the cyclometallating ligands contain fluoro, sulfane or sulfone groups is reported. The conjugate acids of the C^N ligands in the complexes are 2-(4-fluorophenyl)pyridine (H1), 2-(4-methylsulfonylphenyl)pyridine (H3), 2-(4-(t)butylsulfanylphenyl)pyridine (H4), 2-(4-(t)butylsulfonylphenyl)pyridine (H5), 2-(4-(n)dodecylsulfanylphenyl)pyridine (H6), 2-(4-(n)dodecylsulfonylphenyl)pyridine (H7). The single crystal structures of H3 and H5 are described. [Ir(C^N)2(bpy)][PF6] with C^N = 1, 3, 4, 5 and 7 were prepared from the appropriate [Ir2(C^N)4Cl2] dimer and bpy; the structure of [Ir2(3)4Cl2]·2CH2Cl2 was determined. [Ir(6)2(bpy)][PF6] was prepared by nucleophilic substitution starting from [Ir(1)2(bpy)][PF6]. The [Ir(C^N)2(bpy)][PF6] complexes have been characterized by NMR, IR, absorption and emission spectroscopic and mass spectrometric methods. The single crystal structures of enantiomerically pure Δ-[Ir(1)2(bpy)][PF6] and of rac-4{[Ir(1)2(bpy)][PF6]}·Et2O·2CH2Cl2 are described, and the differences in inter-cation packing in the structures compared. [Ir(1)2(bpy)][PF6], [Ir(4)2(bpy)][PF6] and [Ir(6)2(bpy)][PF6] (fluoro and sulfane substituents) are yellow emitters (λ(em)(max) between 557 and 577 nm), and the room temperature solution emission spectra are broad. The sulfone derivatives [Ir(3)2(bpy)][PF6], [Ir(5)2(bpy)][PF6] and [Ir(7)2(bpy)][PF6] are green emitters and the emission spectra are structured (λ(em)(max) = 493 and 523 to 525 nm). High photoluminescence quantum yields (PLQYs) of 64-74% are observed for the sulfone complexes in degassed solutions. The emission lifetimes for the three complexes containing sulfone substituents are an order of magnitude longer (2.33 to 3.36 μs) than the remaining complexes (0.224 to 0.528 μs). Emission spectra of powdered solid samples have also been recorded; the broad emission bands have values of λ(em)(max) in the range 532 to 558 nm, and PLQYs for the powdered compounds are substantially lower (≤23%) than in solution. Trends in the redox potentials for the [Ir(C^N)2(bpy)][PF6] complexes are in accord with the observed emission behaviour." @default.
• W2051279896 created "2016-06-24" @default.
• W2051279896 creator A5020171294 @default.
• W2051279896 creator A5030849346 @default.
• W2051279896 creator A5057669589 @default.
• W2051279896 creator A5068123855 @default.
• W2051279896 date "2014-01-01" @default.
• W2051279896 modified "2023-10-14" @default.
• W2051279896 title "Green-emitting iridium(<scp>iii</scp>) complexes containing sulfanyl- or sulfone-functionalized cyclometallating 2-phenylpyridine ligands" @default.
• W2051279896 cites W1968103014 @default.
• W2051279896 cites W1979368277 @default.
• W2051279896 cites W1981958856 @default.
• W2051279896 cites W1983824817 @default.
• W2051279896 cites W1989723394 @default.
• W2051279896 cites W1990496513 @default.
• W2051279896 cites W1992161147 @default.
• W2051279896 cites W1993821628 @default.
• W2051279896 cites W2011578322 @default.
• W2051279896 cites W2013767827 @default.
• W2051279896 cites W2015007912 @default.
• W2051279896 cites W2015589783 @default.
• W2051279896 cites W2017702218 @default.
• W2051279896 cites W2019265638 @default.
• W2051279896 cites W2020228270 @default.
• W2051279896 cites W2023416956 @default.
• W2051279896 cites W2024518799 @default.
• W2051279896 cites W2025687124 @default.
• W2051279896 cites W2027104358 @default.
• W2051279896 cites W2031451876 @default.
• W2051279896 cites W2032842297 @default.
• W2051279896 cites W2036994707 @default.
• W2051279896 cites W2057555813 @default.
• W2051279896 cites W2057830365 @default.
• W2051279896 cites W2060517372 @default.
• W2051279896 cites W2064949605 @default.
• W2051279896 cites W2066097993 @default.
• W2051279896 cites W2089137363 @default.
• W2051279896 cites W2090219967 @default.
• W2051279896 cites W2093840577 @default.
• W2051279896 cites W2101743419 @default.
• W2051279896 cites W2103107665 @default.
• W2051279896 cites W2111614910 @default.
• W2051279896 cites W2116514934 @default.
• W2051279896 cites W2131350133 @default.
• W2051279896 cites W2134595462 @default.
• W2051279896 cites W2142594455 @default.
• W2051279896 cites W2146946547 @default.
• W2051279896 cites W2152990534 @default.
• W2051279896 cites W2155523679 @default.
• W2051279896 cites W2156665925 @default.
• W2051279896 cites W2158258196 @default.
• W2051279896 cites W2160790360 @default.
• W2051279896 cites W2164926165 @default.
• W2051279896 cites W2240909504 @default.
• W2051279896 cites W2316340166 @default.
• W2051279896 cites W2330281130 @default.
• W2051279896 cites W2950124370 @default.
• W2051279896 cites W2952221943 @default.
• W2051279896 doi "https://doi.org/10.1039/c3dt53626b" @default.
• W2051279896 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24519155" @default.
• W2051279896 hasPublicationYear "2014" @default.
• W2051279896 type Work @default.
• W2051279896 sameAs 2051279896 @default.
• W2051279896 citedByCount "36" @default.
• W2051279896 countsByYear W20512798962014 @default.
• W2051279896 countsByYear W20512798962015 @default.
• W2051279896 countsByYear W20512798962016 @default.
• W2051279896 countsByYear W20512798962017 @default.
• W2051279896 countsByYear W20512798962018 @default.
• W2051279896 countsByYear W20512798962019 @default.
• W2051279896 countsByYear W20512798962020 @default.
• W2051279896 countsByYear W20512798962021 @default.
• W2051279896 countsByYear W20512798962022 @default.
• W2051279896 crossrefType "journal-article" @default.
• W2051279896 hasAuthorship W2051279896A5020171294 @default.
• W2051279896 hasAuthorship W2051279896A5030849346 @default.
• W2051279896 hasAuthorship W2051279896A5057669589 @default.
• W2051279896 hasAuthorship W2051279896A5068123855 @default.
• W2051279896 hasBestOaLocation W20512798961 @default.
• W2051279896 hasConcept C115624301 @default.
• W2051279896 hasConcept C153642686 @default.
• W2051279896 hasConcept C155647269 @default.
• W2051279896 hasConcept C161790260 @default.
• W2051279896 hasConcept C178790620 @default.
• W2051279896 hasConcept C185592680 @default.
• W2051279896 hasConcept C188027245 @default.
• W2051279896 hasConcept C2778806918 @default.
• W2051279896 hasConcept C2779485729 @default.
• W2051279896 hasConcept C2779546866 @default.
• W2051279896 hasConcept C528581852 @default.
• W2051279896 hasConcept C71240020 @default.
• W2051279896 hasConcept C8010536 @default.
• W2051279896 hasConceptScore W2051279896C115624301 @default.
• W2051279896 hasConceptScore W2051279896C153642686 @default.
• W2051279896 hasConceptScore W2051279896C155647269 @default.
• W2051279896 hasConceptScore W2051279896C161790260 @default.
• W2051279896 hasConceptScore W2051279896C178790620 @default.
• W2051279896 hasConceptScore W2051279896C185592680 @default.

• next