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• W2051280928 abstract "Neutron diffraction techniques have been used to investigate a series of V2O5 containing glasses, viz. P2O5V2O5, BaOV2O5 and PbOV2O5. In order to yeild a high resolution real space correlation function, conventional reactor measurements have been supplemented by high momentum transfer data obtained with the Harwell Linac total scattering spectrometer. The vanadate network in all the glasses studied is composed of distorted, interconnected, VO5 trigonal bipyramids/tetragonal pyramids. PO4 tetrahedra are also present in the P2O5V2O5 glass network, the mean PO bond length being 1.536 Å. Vitreous BaOV2O5 and PbOV2O5 show no well defined barium or lead correlations, suggesting that these heavy metal ions exist randomly in holes in the vitreous network." @default.
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• W2051280928 date "1985-12-01" @default.
• W2051280928 modified "2023-10-17" @default.
• W2051280928 title "A neutron diffraction investigation of the structure of phosphorus, barium and lead vanadate glasses" @default.
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• W2051280928 doi "https://doi.org/10.1016/0022-3093(85)90009-2" @default.
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