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- W2051282012 abstract "The kinetics of oxidation of diethanolamine and triethanolamine by potassium ferrate (VI) in alkaline liquids at a constant ionic strength has been studied spectrophotometrically in the temperature range of 278.2 K -293.2 K . The reaction shows first order dependence on potassium ferrate (VI) , first order dependence on each reductant, The observed rate constant ( k obs ) decreases with the increase in [ OH - ], the reaction is negative fraction order with respect to [ OH - ]. A plausible mechanism is proposed and the rate equations derived from the mechanism can explain all the experimental results. The rate constants of the rate-determining step and the thermodynamic activation parameters are calculated." @default.
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- W2051282012 date "2011-01-01" @default.
- W2051282012 modified "2023-10-12" @default.
- W2051282012 title "Kinetics and Mechanism of Oxidation of Diethanolamine and Triethanolamine by Potassium Ferrate" @default.
- W2051282012 doi "https://doi.org/10.1155/2011/267894" @default.
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