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- W2051286331 abstract "We demonstrated the nanocharacterization and nanofabrication of a Nafion thin film using atomic force microscopy (AFM). AFM images showed that the Nafion molecules form nanoclusters in water, in 5% methanol, and in acetic acid. Young's modulus E of a Nafion film was estimated by sequential force curve measurements in water and in 5% methanol on one sample surface. Ewater/E5% methanol was 1.75 +/- 0.40, so the film was much softer in 5% methanol than in water. Even when solvent was replaced from 5% methanol to water, Young's modulus was not recovered soon. We showed the first example of the mechanical properties of a Nafion film on the nanoscale. Furthermore, we succeeded in fabricating 3D nanostructures on a Nafion surface by AFM nanolithography in liquids. Our results showed the new potential of the AFM nanolithography of a polymer film by softening the molecules in liquids." @default.
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- W2051286331 date "2006-03-01" @default.
- W2051286331 modified "2023-09-30" @default.
- W2051286331 title "Nanocharacterization and Nanofabrication of a Nafion Thin Film in Liquids by Atomic Force Microscopy" @default.
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- W2051286331 doi "https://doi.org/10.1021/la051926t" @default.
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