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- W2051287758 abstract "A new, general and straightforward method for the enantiospecific synthesis of 9,10-dihalocamphors (including mixed derivatives) is reported and exemplified for the preparation of (+)-9,10-dibromocamphor (a well-known chiral intermediate) as well as (+)-9-bromo-10-chlorocamphor and (+)-9-bromo-10-iodocamphor (novel mixed dihalides). Our approach is based on a key stereocontrolled tandem electrophilic addition - Wagner-Meerwein rearrangement of optically pure 3-endo-(halomethyl)-3-methyl-2-methylenenorbornan-1-ols, which are easily obtained from readily accessible 9-halocamphors." @default.
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- W2051287758 date "2004-01-01" @default.
- W2051287758 modified "2023-10-16" @default.
- W2051287758 title "Enantiospecific Synthesis of 9,10-Dihalocamphors" @default.
- W2051287758 doi "https://doi.org/10.1055/s-2003-43347" @default.
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