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- W2051289625 endingPage "137" @default.
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- W2051289625 abstract "Discovering new carbon building blocks is very significant to advance transition-metal-catalyzed cycloadditions for the synthesis of various-sized ring compounds. A new seven-carbon building block from buta-1,3-dienylcyclopropanes (BDCPs) has been developed, showing that, under the catalysis of [Rh(CO)(2)Cl](2), BDCPs react with CO to give [7 + 1] cycloaddition products, cyclooctadienones. The present [7 + 1] reaction provides an efficient entry to the synthetically challenging eight-membered carbocyclic skeleton, which is present in many natural products of medicinal and biological significance." @default.
- W2051289625 created "2016-06-24" @default.
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- W2051289625 date "2010-11-24" @default.
- W2051289625 modified "2023-10-16" @default.
- W2051289625 title "Rh-Catalyzed [7 + 1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones" @default.
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- W2051289625 doi "https://doi.org/10.1021/ol102700m" @default.
- W2051289625 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21105743" @default.
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